High-resolution stimulated Raman-spectrum of F2

Year: 1994

Authors: Martinez R.Z., Bermejo D., Santos J., Cancio P.

Autors Affiliation: Instituto de Estructura de la Materia, Consejo Superior de Investigaciones Cientificas

Abstract: The high-resolution stimulated Raman spectrum of F-2 has been recorded with a quasi cw technique. Q branches of the fundamental and first hot band have been fully resolved. Forty-one transitions of the Q branch of the fundamental up to J = 43 have been measured, in addition to 21 transitions of the O and S branches of this band. Twenty-one transitions of the Q branch of the first hot band up to J = 27 have also been measured. From the analysis of these data a more accurate set of molecular parameters for the v = O, v = 1, and v = 2 states of this molecule has been derived. From our data and some previous fluorescence data a new set of equilibrium parameters is also proposed. (C) 1994 Academic Press, Inc.

Journal/Review: JOURNAL OF MOLECULAR SPECTROSCOPY

Volume: 168 (2)      Pages from: 343  to: 349

KeyWords: Molecular Spectroscopy; Stimulated Raman;
DOI: 10.1006/jmsp.1994.1283

Citations: 19
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