Broadening of CH3F in presence of stark fields .1. Self-broadening and self-shifting of isolated components
Year: 1997
Authors: Lemaire V., Dore L., Cazzoli G., Buffa G., Tarrini O., Belli S.
Autors Affiliation: Dipartimento di Chimica dell\’Universitą di Bologna, Bologna, italy; Dipartimento di Fisica dell\’Universitą di Pisa, Pisa, Italy
Abstract: Self-broadening and shifting of methyl fluoride (CH3F)-C-12 have been investigated in the 50-408 GHz range for the rotational transitions J=0–>1, J=1–>2, J=2–>3, J=5–>6, and J=7–>8 and for their Delta M-0 and Delta M=+/-1 Stark components, as they were resolved by an appropriate field. The different results obtained for M-degenerated and M-resolved cases, as well as the M dependence of the results has been interpreted theoretically within semiclassical perturbative approximations. Evidence of collisional coupling effects between Stark components was obtained. (C) 1997 American Institute of Physics.
Journal/Review: JOURNAL OF CHEMICAL PHYSICS
Volume: 106 (22) Pages from: 8995 to: 9003
KeyWords: pressure broadening; methyl fluoride; Stark effectDOI: 10.1063/1.474032Citations: 9data from “WEB OF SCIENCE” (of Thomson Reuters) are update at: 2024-11-10References taken from IsiWeb of Knowledge: (subscribers only)Connecting to view paper tab on IsiWeb: Click hereConnecting to view citations from IsiWeb: Click here