Self-collisional coupling and broadening in the asymmetric rotor CHF2Cl
Year: 1995
Authors: Cazzoli C., Cludi L., Cotti G., Degli Esposti C., Buffa G., Tarrini O.
Autors Affiliation: Dipartimento di Chimica dell’Università di Bologna, Bologna Italy; Dipartimento di Fisica dell’Università di Pisa, Pisa Italy
Abstract: The line shape of 15 selected CHF2Cl rotational transitions is studied in the 59–1049 GHz frequency region. Collisional broadening parameters are measured and compared to semiclassical calculations. For some pairs of lines a large collisional coupling effect is observed and analyzed. A semiclassical theoretical model is presented allowing calculations of the coupling parameters in
good agreement with measurements
Journal/Review: JOURNAL OF CHEMICAL PHYSICS
Volume: 102 (3) Pages from: 1149 to: 1156
KeyWords: spectroscopy; pressure broadening; collisional coupling; asymmetric rotor; DOI: 10.1063/1.469173Citations: 18data from “WEB OF SCIENCE” (of Thomson Reuters) are update at: 2024-11-24References taken from IsiWeb of Knowledge: (subscribers only)Connecting to view paper tab on IsiWeb: Click hereConnecting to view citations from IsiWeb: Click here